许鹏飞 (教授)★
姓 名 |
许鹏飞 |
所属部门 |
有机化学第六研究所 |
职 称 |
教授 |
导师类别 |
博士生导师 |
研究方向 |
不对称合成,不对称催化反应及天然产物全合成 | ||
联系方式 |
0931-8912281,0931-8912374(办) xupf@lzu.edu.cn |
教育背景、工作经历
2015-至今 兰州大学萃英学院执行院长
2009-2015 兰州大学教务处处长
2003-至今 bet365提现要多久、功能有机分子化学国家重点实验室,教授
2003-2004 日本名古屋大学物质材料科学国际研究中心(K. Tatsumi合作教授),访问教授
1999-2001 台湾中兴大学,博士后(陆大荣教授)
1996-1998 兰州大学,理学博士(张自义教授)
1992-1994 兰州大学,理学硕士(吴绍祖教授)
1983-1987 兰州大学,化学系有机化学专业,理学学士(李瑜教授)
· 荣誉奖励
2016兰州大学国华杰出学者奖;
2014全国宝钢优秀教师奖;
2014 甘肃省科技进步一等奖(第一完成人);
2013 兰州大学“师德标兵”,甘肃省“陇原师德先进个人”称号;
2012 金川集团科技进步一等奖,国务院政府特殊津贴;
2010 甘肃省自然科学一等奖(第一完成人);
2009 入选甘肃省领军人才,Thieme Chemistry Journal Award;
2005 入选教育部“新世纪优秀人才支持计划”、甘肃省“555”创新人才;
2002第九届甘肃省青年教师成才奖,甘肃省科技进步三等奖两项。
· 研究兴趣
1)α-氨基酸的不对称合成及方法研究;
2)有机小分子催化的不对称串联反应的研究;
3)天然产物结构导向的有机小分子催化反应的研究;
4)可见光催化的有机反应研究;
5) 新型可见光催化剂的设计与应用;
6)新型浮选剂的研发。
· 代表成果
1. “Asymmetric Catalytic Cascade Reactions for Constructing Diverse Scaffolds and Complex Molecules”. Wang, Y.; Lu, H.;Xu, P.-F. *Acc. Chem. Res.2015, 48, 1832.
2. “Synthesis of a-Amino Acids Based on Chiral Tricycloiminolactone Derived from Natural (+)-Camphor”. Luo, Y.-C.; Zhang, H.-H.; Wang, Y.;Xu, P.-F.*Acc. Chem. Res.2010, 43, 1317.
3. “Rationally Designed Multifunctional Supramolecular Iminium Catalysis: Direct Vinylogous Michael Addition of Unmodified Linear Dienol Substrates”.Gu,Y.; Wang,Y.; Yu,T.-Y.; Liang,Y.-M.;* Xu, P.-F.*Angew. Chem., Int. Ed.2014, 53, 14128.
4. “Hydrogen-Bond-Mediated Supramolecular Iminium Ion Catalysis”.Wang,Y.; Yu,T.-Y.; Zhang,H.-B.; Luo,Y.-C;Xu, P.-F.* Angew. Chem., Int. Ed.2012, 51, 12339.
5. “Asymmetric Organocatalytic Relay Cascades: Catalyst-Controlled Stereoisomer Selection in the Synthesis of Functionalized Cyclohexanes”.Wang,Y.; Han,R.-G.; Zhao,Y.-L.; Yang,S.; Dixon,D. J.;Xu, P.-F.*Angew. Chem., Int. Ed.2009, 48, 9834.
6. “Catalytic Cascade Reactions”.Xu, P.-F., Wang, W., Eds.; John Wiley & Sons: Canada, 2014.
7. “Iridium(1+),Bis(acetonitrile)bis[2-[5-(1,1-dimethylethyl)-2-benzothiazolyl-kN3]phenyl-kC]-,(OC-6-13-Λ)Hexafluorophosphate(1-) (1:1)”. Xu, G.-Q.; Liang, H.; Xu, P.-F.*Encyclopedia of reagents for Organic Synthesis [Online], John Wiley & Sons Ltd., 2017.
8. “N?Heterocyclic Carbene-Catalyzed Atom-Economical and Enantioselective Construction of the C?S Bond: Asymmetric Synthesis of Functionalized Thiochromans”.Lu, H.; Zhang, J.-L.; Liu, J.-Y.; Li, H.-Y.;Xu, P.-F.*ACS Catal.2017, 7, 7797.
9. “3,4,5-Trimethylphenol and Lewis Acid Dual-Catalyzed Cascade Ring-Opening/Cyclization: Direct Synthesis of Naphthalenes”.Ma, H.; Hu, X.-Q.;* Luo, Y.-C.;Xu, P.-F.*Org. Lett.2017, 19, 6666.
10. “Visible-Light-Induced Aza-Pinacol Rearrangement: Ring Expansion of Alkylidenecyclopropanes”.Liu, W.-D.; Xu, G.-Q.; Hu, X.-Q.;Xu, P.-F.*Org. Lett.2017, 19,6291.
11. “Highly Enantioselective Construction of Hajos-Wiechert Ketone Skeletons via an Organocatalytic Vinylogous Michael/Stetter Relay Sequence”. Jia, Z.-L.; Wang, Y.; Zhao, C.-G.; Zhang, X.-H.;Xu, P.-F.*Org. Lett.2017, 19, 2130.
12. “Quaternary Carbon Center Forming Formal [3+3] Cycloaddition Reaction via Bifunctional Catalysis: Asymmetric Synthesis of Spirocyclohexene Pyrazolones”. Liu, J.-Y.; Zhao, J.; Zhang, J.-L.;Xu, P.-F.*Org. Lett.2017, 19, 1846.
13. “Synthesis of Fused Pyran Derivatives via Visible-Light-Induced Cascade Cyclization of 1,7-Enynes with Acyl Chlorides”. Li, C.-G.; Xu,G.-Q;Xu, P.-F.*Org. Lett.2017, 19, 512.
14. “Rh(II) Catalyzed High Order Cycloadditions of 8-Azaheptafulvenes with N-Sulfonyl 1,2,3-Triazloes or α-Oxo Diazocompounds”. Chen, W.; Bai, Y.-L.; Luo, Y.-C.;Xu, P.-F.*Org. Lett.2017, 19, 364.
15. “Lewis acid catalyzed diastereoselective [3+4]-annulation of donor-acceptor cyclopropanes with anthranils: synthesis of tetrahydro-1-benzazepine derivatives”.Wang, Z.-H.; Zhang, H.-H.;* Wang, D.-M.;Xu, P.-F.; Luo, Y.-C.* Chem.Commun.2017, 53, 8521.
16. “Kinetic resolution via supramolecular iminium catalysis: multiactivation enables the asymmetric synthesis of beta-aryl substituted aldehydes and densely functionalized cyclohexanes”. Jia, Z.-L.; Wang, Y.;Xu, G.-Q.;Xu, P.-F.*Chem.Commun.2017, 53, 4938.
17. “Metal-Free, Visible-Light-Promoted Synthesis of 3-Phosphorylated Coumarins via Radical C?P/C?C Bond Formation”.Liu, D.; Chen, J.-Q.; Wang, X.-Z.;Xu, P.-F.*Adv. Synth. Catal.2017, 359, 2773.
18. “Aroyl chlorides as novel acyl radical precursors via visible-light photoredox catalysis”. Xu, S.-M.; Chen, J.-Q.; Liu, D.; Bao, Y.; Liang, Y.-M.;Xu, P.-F.*Org. Chem. Front.2017, 4, 1331.