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曹小平 (教授)★

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姓  名
曹小平
所属部门
有机化学第四研究所
职  称
教授
导师类别
博士生导师
研究方向
有机合成化学
联系方式

曹小平,1982年本科毕业于兰州大学化学系后留校任助教、讲师, 1989年在职获硕士学位1993-1997年在香港中文大学获博士学位并完成博士后研究即返兰州大学任副教授,2002年任教授、博士生导师。200320082013受教育部和德国科学研究基金会(DFG)资助在德国Bielefeld大学合作科研,任访问教授。曾为国家自然科学基金委员会创新研究群体国家重点基础研究发展计划(973计划)”骨干成员, 现为教育部长江学者创新团队发展计划骨干成员。完成和主持国家自然科学基金委员会面上项目、及与香港研究资助局联合科研资助基金(NSFC/RGC)项目,教育部高等学校博士学科点专项科研基金,国家教委骨干教师基金优秀年轻教师基金回国人员科研启动基金中国博士后科学基金甘肃省自然科学基金等多项科研项目。教学成果曾获甘肃省教育厅级奖及兰州大学奖。目前主要研究兴趣为天然产物全合成及其方法学,有机功能分子的设计合成及性质研究,迄今已在Chem. Sci., Chem. Commun., Chem. Eur. J., Chem. Asian J., Org. Lett., J. Org. Chem., Adv. Synth. Catal., Appl. Catal. B: Environ.等国内外刊物上发表学术论文多篇。

近五年代表性论文

1 “o-Quinones Derived from Tribenzotriquinacenes: Functionalization of Inner Bay Positions and Use for Single-Wing Extensions”, Yu-Fei Zhang, Wan-Fa Tian, Xiao-Ping Cao*, Dietmar Kuck*, and Hak-Fun Chow*, J. Org. Chem. 2016, 81, 2308-2319.

2 “Triphenylethylene-based Fluorophores: Facile Preparation and Fullcolor Emission in both Solution and Solid States”, Wei Wen, Zi-Fa Shi, Xiao-Ping Cao*, and Nian-Sheng Xu, Dyes and Pigments 2016, 132, 282-290.

3 Direct and Short Construction of the ACDE Ring System of Daphenylline, Wei Wang, Guo-Ping Li, Shao-Feng Wang, Zi-Fa Shi, and Xiao-Ping Cao*, Chem. Asian J. 2015, 10, 377-382.

4 Cyclopropenes for the Synthesis of Cyclopropane-Fused Dihydroquinolines and Benzazepines, Hui-Xin Luo, You-Hong Niu, Xiao-Ping Cao*, and Xin-Shan Ye*, Adv. Synth. Catal. 2015, 357, 2893-2902.

5 Versatile Syntheses of Hemi-Cryptophanes and a Metallo-Cryptophane from a Hexa-Functionalized C3v-Symmetrical Tribenzotriquinacene (TBTQ) Derivative, Jun Wei, Zhi-Min Li, Xiao-Jie Jin, Xiao-Jun Yao, Xiao-Ping Cao*, Hak-Fun Chow*, and Dietmar Kuck*, Chem. Asian J. 2015, 10, 1150-1158.

6 Facile Preparation of ɑ-Cyano-ɑ,ω-Diaryloligovinylenes: A New Class of Color-Tunable Solid Emitters, Peng An, Nian-Sheng Xu, Hao-Li Zhang, Xiao-Ping Cao*, Zi-Fa Shi*, and Wei Wen, Chem. Asian J. 2015, 10, 1959-1966.

7 Formal Synthesis of (±)-Cycloclavine, Wei Wang, Jia-Tian Lu, Hao-Li Zhang, Zi-Fa Shi, Jing Wen, and Xiao-Ping Cao*, J. Org. Chem. 2014, 79, 122-127.

8 A Phosphine-catalyzed Regioselective [3+2] Cycloaddition of Ethyl 5,5-Diarylpenta-2,3,4-trienoate with Aromatic Aldehydes and ɑ,?-Unsaturated Carbonyl Compounds, Lu-Feng Wang, Xiao-Ping Cao*, Zi-Fa Shi*, Peng An, and Hak-Fun Chow, Adv. Synth. Catal. 2014, 356, 3383-3390.

9 Construction of Fused- and Spiro-oxa-[n.2.1] Skeletons by a Tandem Epoxide Rearrangement/intramolecular [3+2] Cycloaddition of Cyclopropanes with Carbonyls, Lu-Feng Wang, Zi-Fa Shi*, Xiao-Ping Cao*, Bao-Sheng Li, and Peng An, Chem. Commun. 2014, 50, 8061-8064.

10 “C3-Symmetrical Tribenzotriquinacene Derivatives: Optical Resolution through Cryptophane Synthesis and Supramolecular Self-Assembly into Nanotubes”, Tao Wang, Yu-Fei Zhang, Qin-Qing Hou, Wen-Rong Xu, Xiao-Ping Cao*, Hak-Fun Chow*, and Dietmar Kuck*, J. Org. Chem. 2013, 78, 1062-1069.

11 “FeCo–Nx Embedded Graphene as High Performance Catalysts for Oxygen Reduction Reaction”, Xiao-Gang Fu, Yan-Ru Liu, Xiao-Ping Cao*, Jutao Jin, Qiao Liu, and Junyan Zhang*, Appl. Catal. B: Environ. 2013, 130-131, 143-151.

12 “Direct Syntheses of Spiro- and Fused-Hydrofurans by a Tunable Tandem Semipinacol Rearrangement/Oxa-Michael Addition Protocol”, Bao-Sheng Li, Wen-Xing Liu, Qing-Wei Zhang, Shao-Hua Wang, Fu-Ming Zhang, Shu-Yu Zhang, Yong-Qiang Tu*, and Xiao-Ping Cao*, Chem. Eur. J. 2013, 19, 5246-5249.

13 Copper(I)-catalyzed Intramolecular [2+2] Cycloaddition of 1,6-Enyen-derived Ketenimine: an Efficient Construction of Strained and Bridged 7-Substituted-3-heterobicyclo[3.1.1]heptan-6-one, Bao-sheng Li, Bin-Miao Yang, Shao-Hua Wang, Yong-Qiang Zhang, Xiao-Ping Cao*, and Yong-Qiang Tu*, Chem. Sci., 2012, 3, 1975-1979.

14 Synthesis of Polyisoprene Terpenoid Dendrons and their Applications in Oligo(phenylene ethynylene)s as ‘Shells’, Wen-Yu Chai, Zi-Fa Shi, Peng An, Wei Wang, Lu-Feng Wang, and Xiao-Ping Cao*, Chem. Asian J. 2012, 7, 143-155.

15 Single-wing Extended Tribenzotriquinacenes via Bowl-shaped Dehydrobenzene and Isobenzofuran Tribenzotriquinacene Derivatives, Wen-Xue Niu, Er-Qun Yang, Zi-Fa Shi, Xiao-Ping Cao*, and Dietmar Kuck*, J. Org. Chem. 2012, 77, 1422-1434.